International Journal of Innovative Approaches in Science Research
Abbreviation: IJIASR | ISSN (Print): 2602-4810 | ISSN (Online): 2602-4535 | DOI: 10.29329/ijiasr

Original article    |    Open Access
International Journal of Innovative Approaches in Science Research 2018, Vol. 2(1) 9-24

DSSC'ler için NNN ligantlar ile kararlaştırılmış Rutenyum malzemeler

Osman Dayan, Namık Özdemir, Fahrettin Yakuphanoğlu, Zafer Şerbetci & Ali Bilici

pp. 9 - 24   |  DOI: https://doi.org/10.29329/ijiasr.2018.132.2

Published online: March 29, 2018  |   Number of Views: 225  |  Number of Download: 793


Abstract

Bu çalışmada 2,6-bis(benzimidazol)piridinil (NNN) ligantlar ile kararlaştırılmış yeni rutenyum nano partüküllerin üretildi. Malzemeler NMR, IR, SEM-EDX, TEM ve XRD gibi teknikler kullanılarak yapıları hakkında bilgi edinildi ve boya duyarlı güneş hücrelerinin hazırlanmasında kullanıldı. 

Keywords: Boya duyarlı güneş hücresi, Rutenyum, I-V karakteristiği


How to Cite this Article

APA 6th edition
Dayan, O., Ozdemir, N., Yakuphanoglu, F., Serbetci, Z. & Bilici, A. (2018). DSSC'ler için NNN ligantlar ile kararlaştırılmış Rutenyum malzemeler . International Journal of Innovative Approaches in Science Research, 2(1), 9-24. doi: 10.29329/ijiasr.2018.132.2

Harvard
Dayan, O., Ozdemir, N., Yakuphanoglu, F., Serbetci, Z. and Bilici, A. (2018). DSSC'ler için NNN ligantlar ile kararlaştırılmış Rutenyum malzemeler . International Journal of Innovative Approaches in Science Research, 2(1), pp. 9-24.

Chicago 16th edition
Dayan, Osman, Namik Ozdemir, Fahrettin Yakuphanoglu, Zafer Serbetci and Ali Bilici (2018). "DSSC'ler için NNN ligantlar ile kararlaştırılmış Rutenyum malzemeler ". International Journal of Innovative Approaches in Science Research 2 (1):9-24. doi:10.29329/ijiasr.2018.132.2.

References
  1. B. Oregan, M. Gratzel, A Low-Cost, High-Efficiency Solar-Cell Based on Dye-Sensitized Colloidal Tio2 Films, Nature, 353 (1991) 737-740. [Google Scholar]
  2. S.M. Feldt, E.A. Gibson, E. Gabrielsson, L. Sun, G. Boschloo, A. Hagfeldt, Design of Organic Dyes and Cobalt Polypyridine Redox Mediators for High-Efficiency Dye-Sensitized Solar Cells, J Am Chem Soc, 132 (2010) 16714-16724. [Google Scholar]
  3. K.R. Seddon, Ruthenium, Coordin Chem Rev, 41 (1982) 79-157. [Google Scholar]
  4. H.N. Yi, J.A. Crayston, J.T.S. Irvine, Ruthenium complexes of 2-(2 '-pyridyl) benzimidazole as photosensitizers for dye-sensitized solar cells, Dalton T, DOI 10.1039/b208289f(2003) 685-691. [Google Scholar]
  5. D.B. Kuang, C. Klein, S. Ito, J.E. Moser, R. Humphry-Baker, S.M. Zakeeruddin, M. Gratzel, High molar extinction coefficient ion-coordinating ruthenium sensitizer for efficient and stable mesoscopic dye-sensitized solar cells, Adv Funct Mater, 17 (2007) 154-160. [Google Scholar]
  6. M.K. Nazeeruddin, A. Kay, I. Rodicio, R. Humphrybaker, E. Muller, P. Liska, N. Vlachopoulos, M. Gratzel, Conversion of Light to Electricity by Cis-X2bis(2,2'-Bipyridyl-4,4'-Dicarboxylate)Ruthenium(Ii) Charge-Transfer Sensitizers (X = Cl-, Br-, I-, Cn-, and Scn-) on Nanocrystalline Tio2 Electrodes, J Am Chem Soc, 115 (1993) 6382-6390. [Google Scholar]
  7. X.M. Xiao, M.A. Haga, T. Matsumurainoue, Y. Ru, A.W. Addison, K. Kano, Synthesis and Proton Transfer-Linked Redox Tuning of Ruthenium(Ii) Complexes with Tridentate 2,6-Bis(Benzimidazol-2-Yl)Pyridine Ligands, J Chem Soc Dalton, DOI Doi 10.1039/Dt9930002477(1993) 2477-2484. [Google Scholar]
  8. O. Kohle, S. Ruile, M. Gratzel, Ruthenium(II) charge-transfer sensitizers containing 4,4'-dicarboxy-2,2'-bipyridine. Synthesis, properties, and bonding mode of coordinated thio- and selenocyanates, Inorg Chem, 35 (1996) 4779-4787. [Google Scholar]
  9. S. Ruile, O. Kohle, P. Pechy, M. Gratzel, Novel sensitisers for photovoltaic cells. Structural variations of Ru(II) complexes containing 2,6-bis(1-methylbenzimidazol-2-yl)pyridine, Inorg Chim Acta, 261 (1997) 129-140. [Google Scholar]
  10. M.K. Nazeeruddin, E. Muller, R. Humphry-Baker, N. Vlachopoulos, M. Gratzel, Redox regulation in ruthenium(II) polypyridyl complexes and their application in solar energy conversion, J Chem Soc Dalton, DOI Doi 10.1039/A704242f(1997) 4571-4578. [Google Scholar]
  11. S.C. Yu, S.J. Hou, W.K. Chan, Synthesis, metal complex formation, and electronic properties of a novel conjugate polymer with a tridentate 2,6-bis(benzimidazol-2-yl)pyridine ligand, Macromolecules, 32 (1999) 5251-5256. [Google Scholar]
  12. M.A. Haga, K. Wang, N. Kato, H. Monjushiro, Electrochemical properties of dinuclear Ru complex Langmuir-Blodgett films towards molecular electronics, Mol Cryst Liq Crys A, 337 (1999) 89-92. [Google Scholar]
  13. K.Z. Wang, M.A. Haga, Chemical transformation of amphiphilic Ru complexes containing 2,6-pyridinedicarboxylate at the air-water interface, Mol Cryst Liq Cryst, 342 (2000) 225-230. [Google Scholar]
  14. L. Mishra, R. Sinha, Mononuclear and binuclear ruthenium(III) polypyridyl complexes containing 2,6-bis(2 '-benzimidazyl)-pyridine as co-ligand: Synthesis, spectroscopic properties and redox activity, Indian J Chem A, 39 (2000) 1131-1139. [Google Scholar]
  15. V.G. Vaidyanathan, B.U. Nair, Synthesis, characterization and DNA binding studies of a ruthenium(II) complex, J Inorg Biochem, 91 (2002) 405-412. [Google Scholar]
  16. M. Haga, T. Takasugi, A. Tomie, M. Ishizuya, T. Yamada, M.D. Hossain, M. Inoue, Molecular design of a proton-induced molecular switch based on rod-shaped Ru dinuclear complexes with bis-tridentate 2,6-bis(benzimidazol-2-yl) pyridine derivatives, Dalton T, DOI 10.1039/b300130j(2003) 2069-2079. [Google Scholar]
  17. V.G. Vaidyanathan, B.U. Nair, Synthesis, characterization and electrochemical studies of mixed ligand complexes of ruthenium(II) with DNA, Dalton T, DOI 10.1039/b502917a(2005) 2842-2848. [Google Scholar]
  18. D. Mishra, A. Barbieri, C. Sabatini, M.G.B. Drew, H.M. Figgle, W.S. Sheldrick, S.K. Chattopadhyay, Tuning of redox potential and visible absorption band of ruthenium(II) complexes of (benzimidazolyl) derivatives: Synthesis, characterization, spectroscopic and redox properties, X-ray structures and DFT calculations, Inorg Chim Acta, 360 (2007) 2231-2244. [Google Scholar]
  19. A. Singh, B. Chetia, S.M. Mobin, G. Das, P.K. Iyer, B. Mondal, Ruthenium monoterpyridine complexes with 2,6-bis(benzimidazol-2-yl)pyridine: Synthesis, spectral properties and structure, Polyhedron, 27 (2008) 1983-1988. [Google Scholar]
  20. J.J. Concepcion, J.W. Jurss, P.G. Hoertz, T.J. Meyer, Catalytic and Surface-Electrocatalytic Water Oxidation by Redox Mediator-Catalyst Assemblies, Angewandte Chemie-International Edition, 48 (2009) 9473-9476. [Google Scholar]
  21. C. Bhaumik, S. Das, D. Saha, S. Dutta, S. Baitalik, Synthesis, Characterization, Photophysical, and Anion-Binding Studies of Luminescent Heteroleptic Bis-Tridentate Ruthenium(II) Complexes Based on 2,6-Bis(Benzimidazole-2-yl)Pyridine and 4'-Substituted 2,2 ':6 ',2 '' Terpyridine Derivatives, Inorg Chem, 49 (2010) 5049-5062. [Google Scholar]
  22. Q.Y. Yu, B.X. Lei, J.M. Liu, Y. Shen, L.M. Xiao, R.L. Qiu, D.B. Kuang, C.Y. Su, Ruthenium dyes with heteroleptic tridentate 2,6-bis(benzimidazol-2-yl)-pyridine for dye-sensitized solar cells: Enhancement in performance through structural modifications, Inorg Chim Acta, 392 (2012) 388-395. [Google Scholar]
  23. A.W. Addison, P.J. Burke, Synthesis of Some Imidazole-Derived and Pyrazole-Derived Chelating-Agents, J Heterocyclic Chem, 18 (1981) 803-805. [Google Scholar]
  24. D. Gonzalez-Galvez, P. Lara, O. Rivada-Wheelaghan, S. Conejero, B. Chaudret, K. Philippot, P.W.N.M. van Leeuwen, NHC-stabilized ruthenium nanoparticles as new catalysts for the hydrogenation of aromatics, Catal Sci Technol, 3 (2013) 99-105. [Google Scholar]